Utilização de resíduos descartáveis de casca de arroz a bagaço de cana de açúcar para fabricação de catalisadores menos poluentes
DOI:
https://doi.org/10.34117/bjdv9n8-056Keywords:
meio ambiente, poluição, catalisador, parâmetros, Fischer-TropschAbstract
A enorme quantidade de resíduos gerados por determinados setores produtivos tem levado pesquisadores a buscar soluções adequadas, com o intuito de atender as questões técnicas, econômicas e ambientais. A necessidade de aproveitamento de resíduos nos processos industriais está acentuada no mundo. Dessa forma, este trabalho estudou resíduos da casca de arroz e do Bagaço de Cana de açúcar geralmente descartáveis para produção de catalisadores menos poluentes ao meio ambiente.
References
AHMARUZZAMAN, M. A review on the utilization of fly ash. Progress in Energy and Combustion Science, v.36, p.327-363, 2010.
ANFRAY, j.; BREMAUD, M.; FONGARLAND, P.; KHODAKOV, A.; JALLAIS, S.; SCHWEICH. Kinetic study and modeling of Fischer–Tropsch reaction over aCo/Al2O3 catalyst in a slurry reactor. Chemical Engineering Science, v. 62, p.5355-5360, 2007.
BARROS JUNIOR. Estimação de parâmetros, modelagem e simulação da síntese de Fischer-Tropsch em reator tubular de leito fixo com catalisador de cobalto. Tese de Doutorado. Universidade Federal do Ceará, 2013.
BOATENG, A. A. SKEETE, D. A. Incineration of rice hull for use as a cementitious material: the Guyana Experience. Cement and Concrete Research, v. 20, p. 795-802, 1990.
BRADY R.C.; PETIT, R. Reactions Of Diazomethane On Transition-Metal Surfaces And Their Relationship To The Mechanism Of The Fischer-Tropsch Reaction.Journal Of The American Chemical Society, v. 102, p. 6181–6182, 1980. BHAGIYALAKSHMI, M.; YUN, L. J.; ANURADHA, R.; JANG, H. T. Utilization of rice husk ash as silica source for the synthesis of mesoporous silicas and their application to CO2 adsorption through TREN/TEPA grafting. Journal of Hazardous Materials. v. 175, p. 928-938, 2010.
CHANG, J.; BAI, L.; TENG, B. ZHANG, R.; YANG, J.; XU, Y.; XIANG, H.; LI, Y. inetic modeling of Fischer–Tropsch synthesis over Fe/Cu/K/SiO2 catalyst in slurry phase reactor. Chemical Engineering Science, v. 62, p.4983 – 4991, 2007.
CORDEIRO, G. C. Utilização de cinzas ultrafinas do bagaço de cana-de-açúcar e da casca de arroz como aditivos minerais em concreto. (tese de doutorado). Universidade Federal do Rio de Janeiro (UFRJ) 2006.
CORDEIRO, G. C.; TOLEDO FILHO, R.D.; FAIRBAIRN, E. M. R. caracterização de cinza do bagaço de cana-de-açúcar para emprego como pozolana em materiais cimentícios. Quim. Nova, v. 32, p.82-86, 2009.
CORTEZ, L., MAGALHÃES, P., HAPP, J., 1992, “Principais subprodutos da agroindústria canavieira e sua valorização”, Revista Brasileira de Energia, v. 2, p. 12-18, 1992.
DALAI, A.K.; DAVIS, B.H. Fischer–Tropsch synthesis: A review of water effects on the performances of unsupported and supported Co catalysts. Applied Catalysis A: General, v. 348, p. 1-15, 2008.
DRY, M. E. The Fischer–Tropsch process: 1950–2000. Catalysis Today, v. 71, p.227–241, 2002.
DRY, M. E. Advances in Fischer Tropsch Chemistry. Industrial & Engineering Chemistry Product Research and Development. v. 15, p. 282, 1976.
FARSHID, G.; HABIBOLLAH, Y.; ZAHRA, M.; MEHMET, S. C. E.; ALI, A. G.; MANSOOR, A. Preparation and characterization of highly pure silica from sedge as agricultural waste and its utilization in the synthesis of mesoporous silica MCM-41. Journal of the Taiwan Institute of Chemical Engineers. In press, 2013.
GUO, Y., ROCKSTRAW, D. A. Activated carbons prepared from rice hull by one-step phosphoric acid activation. Microporous and Mesoporous Materials, v.100, p.12-19, 2006
HUANG, W.; GONG, F.; FAN, M.; HONG, C.; LI, Q. Production of light olefins by catalytic conversion of lignocellulosic biomass with HZSM-5 zeolite impregnated with 6 wt.% lanthanum. Bioresource Technology, v.121, p. 248-255. 2012.
HWANG, Y.K.; CHANG, J.S.; KWON, Y.U.; PARK, S.E.; Nanotechnology in Mesostructured Materials, Studies is Surface Science and Catalysis, v. 146, p. 101, 2003.
JAMES, J. RAO, M. S. Sílica from Rice husk through thermal decomposition, Thermochimica Acta, v. 97. p. 329-336, 1986.
KRISHNARAO, R. V.; SUBRAHMANYAM, J.; JAGADISH, K. T. Studies os the formation of Black particles in Rice sílica ash. Journal of the European ceramic society. v. 21. p. 99-104, 2001.
MANSOURI, M.; MIRZAEI, A. A. SHIRZADI, B.; ATASHI, H.; MANSOURI, M. Modeling and operating conditions optimization of Fischer–Tropsch synthesis in a fixed-bed reactor. Journal of Industrial and Engineering Chemistry. v. 18, p. 1515-1521, 2012.
MARETTO, C.; KRISHNA, R. Modelling of a bubble column slurry reactor for Fischer–Tropsch synthesis. Catalysis Today. v. 52, p.279-289, 1999.
MENDES, F M T; PEREZ, C A C; NORONHA, F B; SOUZA, C D D; CESAR, D V; FREUND, H J; SCHMAL, M. Fischer−Tropsch Synthesis on Anchored Co/Nb2O5/Al2O3 Catalysts: The Nature of the Surface and the Effect on Chain Growth. Journal of Physical Chemistry, v. 110, p. 9155–9163, 2006.
PAULA, M. O. Potencial da cinza do bagaço de cana-de-açúcar como material de substituição parcial de cimento Portland. (dissertação de mestrado). Universidade Federal de Viçosa (UFV) 2006.
PICHLER, H, SCHULZ, H. 14C-Studien zum Reaktionsmechanismus der Fischer-Tropsch Synthese. Erdoel und Kohle, v.23, p.651, 1970.
PONEC, V.; VAN BARNEVELD,W. A. The Role of Chemisorption in Fischer-. Tropsch Synthesis. Ind. Eng. Prod. Res. Dev. v. 18, p. 26, 1979.
POUR, A. N.; HOUSAINDOKHT, M. R.; IRANI, M.; SHAHRI, S. M. K. Size-dependent studies of Fischer–Tropsch synthesis on iron based catalyst: New kinetic model. Fuel. v.116, p. 787-793, 2014.
REAL, C. ALCALA, M. D. CRIADO, J. M. Preparation of sílica from Rice Husks. Journal American Ceramica Society, v. 79, p. 2012-2016, 1996.
RODRIGUES, J. J.; LIMA, L. A.; LIMA, W. S.; RODRIGUES M. G. F.; Fernandes, F. A. N. Fischer-Tropsch synthesis in slurry-phase reactors using Co/SBA-15 catalysts, Brazilian Journal of Petroleum and gas. v.5, p. 149-157, 2011.
RODRIGUES, J. J.; PECCHI, G.; FERNANDES, F. A. N.; RODRIGUES, M. G. F. Ruthenium promotion of Co/SBA-15 catalysts for Fischer-Tropsch synthesis in slurry-phase reactors, Journal of Natural Gas Chemistry, v. 21, p. 722-728, 2012.
RODRIGUES, J. J. Síntese da peneira molecular SBA-15 por métodos de aquecimento distintos e desenvolvimento de catalisadores (Co/SBA-15 e Ru/Co/SBA-15-15) destinados a reação de Fischer-Tropsch. Dissertação de Mestrado – Universidade Federal de Campina Grande, 2011.
RODRIGUES, J. J.; FERNANDES, F.A.N.; RODRIGUES, M. G. F. Study of Co/SBA-15 catalysts prepared by microwave and conventional heating methods and application in Fischer–Tropsch synthesis. Appl. Catal. A. v.468, p.32-37, 2013.
SARI, A.; ZAMANI Y.; TAHERI, S.A. Intrinsic kinetics of Fischer–Tropsch reactions over an industrial Co–Ru/γ-Al2O3 catalyst in slurry phase reactor. Fuel Processing Technology. v.90, p.1305-1313, 2009.
SARUP, B.; WOJCIECHOWSKI, B. W. Studies of the fischer-tropsch synthesis on a colbalt catalyst: III: mechanistic formulation of the kinetics of selectivity for higher hydrocarbon formation. Canadian Journal of Chemical Engineering. v. 67, p. 620-327, 1989. SHI, B; KEOGH,R.A; BURTRON H. D. Fischer-Tropsch synthesis: The formation of branched hydrocarbons in the Fe and Co catalyzed reaction. Journal of Molecular Catalysis A: Chemical. v. 234, p.85-97, 2005.
SHINZATO, M. C.; MONTANHEIRO, T. J.; CARVALHO, F. M. S.; NEGRI, F. A.; YAMAMOTO, J. K.; SILVA, I. S. Síntese de Zeólita a partir de cinzas de bagaço da cana. In: Congresso Brasileiro de engenharia e Ciências dos materiais CBECIMat, Porto de Galinhas-PE, 2008.
SHIVA, M.; ATASHI, H.; TABRIZI, F. F.; MIRZAEI, A. A. Kinetic modeling of Fischer–Tropsch synthesis on bimetallic Fe–Co catalyst with phenomenological based approaches. Journal of Industrial and Engineering Chemistry. v. 18, p. 1112-1121, 2012.
SOUZA, M. F. Rice Hull Dirived silica: Applications in Portland Cement and Mullite Whiskers. Material Research. v. 3, p. 25-30, 2000.
TEODORO, N.; BRAGA, R. M.; AQUINO, F. M.; MELO, V. R. M.; MELO, D. M. A.; BARROS, J. M. F.; MELO, M. A. F. Síntese e caracterização de MCM-41 derivado do resíduo do bagaço da cana-deaçúcar. In: XXIII Congresso IberoAmericano de Catálise. Santa Fé -Argentina, 2012.
TODIC, B.; MA, W.; JACOBS, G.; DAVIS, B. H.; BUKUR, D. B. CO-insertion mechanism based kinetic model of the Fischer–Tropsch synthesis reaction over Re-promoted Co catalyst. Catalysis Today. v. 228, p. 32-39, 2014.
VANNICE, M. A. The catalytic synthesis of hydrocarbons from H2/CO mixtures over the group VIII metals: I: The specific activities and product distributions of supported metals. Journal of Catalysis. v. 37, p. 449-461, 1975.
VESSIA, O. Biofuels from lignocellulosic material – In the Norwegian context Tecnology, Potential and Costs. Norweigian University of Science and Tecnlogy – NTNU, p. 101, 2006.
VLAEV, L.; PETKOV, P.; DIMITROV, A.; GENIEVA, S.; Cleanup of water polluted with crude oil or diesel fuel using Rice husks ash. Journal of the Taiwan Institute of Chemical Engineers, v. 42, p. 957-964, 2011.
ZHAO, E., FENG, J., HUO, Q, FENG, J..G.H., CHMELKA, B.F., STUCKY, G.D. Nonionic triblock copolymer and oligameric surfactant syntheses of highly ordered hydrothermally stable, mesoporous sílica structures. J. Am. Chem. Soc. v.120, p. 6024-6036, 1998.
