Development of composites based on a blend of recycled HDPE/post-consumer PET and bentonite clay

Authors

  • Aline Muniz Lima
  • Gabriel de Sousa Barros
  • Mônica Cristina Celestino Santos
  • Marceli do Nascimento da Conceição
  • Daniele Cruz Bastos
  • Patricia Soares da Costa Pereira
  • Elaine Vidal Dias Gomes Libano

DOI:

https://doi.org/10.34117/bjdv9n4-041

Keywords:

bentonite, polymer blends, composites, HDPE, PET

Abstract

The recycling process is the best way to manage waste polymers. From an economic standpoint, more investigation is needed of the whole recycling process to enhance the competitiveness in these systems. A first step is improved interaction and interfacial adhesion of blends. Polyethylene (PE) and polyethylene terephthalate (PET) are incompatible polymers, so their blends in general have poor properties. Compatibilization is thus a necessary step to obtain blends with good mechanical and barrier properties. In this work, blends of recycled (high density polyethylene) (HDPE) and post-consumer PET, with organophilic bentonite clay acting as compatibilization agent at the interface of the two polymers, were obtained. The proportions of HDPE/PET/bentonite (0, 5, 10 and 15% weight percentage of bentonite) were processed by extrusion. The processed materials were characterized regarding density (ASTM D792-13), melt flow index (MFI, ASTM D1238-13), hardness (ASTM D2240–10), infrared absorption spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results indicated the occurrence of some compatibilization.

References

ASTM D1238-01. AMERICAN SOCIETY FOR TESTING AND MATERIALS. Melt flow Rates of Thermoplastics by Extrusion Plastometer. In: Annual Book of ASTM, 2013.

ASTM D792-13. AMERICAN SOCIETY FOR TESTING AND MATERIALS. Standard Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement. In: Annual Book of ASTM, 2013.

ASTM D2240-05. AMERICAN SOCIETY FOR TESTING AND MATERIALS. Standard Test Method for Rubber Property-Durometer Hardness. In: Annual Book of ASTM, 2013.

DIMITROVA, T.L.; LA MANTIA, F.P.; PILATI, F.; TOSELLI, M.; VALENZA, A.; VISCO, A. On the compatibilization of PET/HHDPE blends through a new class of copolyesters. Polymer, v. 41, p. 4817-4824, 2000.

ORÉFICE, R.L.; VASCONCELOS, W.L; MORAES, M.A.S. Estabilidade de Fases em Blendas de Policarbonato- Poliestireno Avaliada por Micro-FTIR, Análise Térmica e Microscopia Eletrônica de Varredura. Polímeros: Ciência e Tecnologia, v.14, p. 129-133, 2004.

AUBRY, T. An overview on clay-mediated compatibilization of polyethylene/polyamide blends with droplet morphology. Applied Clay Science, v. 175, p. 184-189, 2019.

CHEN, R.S.; AHMAD, S.; GAN, S. Characterization of recycled thermoplastics-based nanocomposites: Polymer-clay compatibility, blending procedure, processing condition, and clay content effects. Composites Part B: Engineering. v. 131, p. 91-99, 2017.

BNDS – Banco Nacional de desenvolvimento. Disponível em <https://www.bndes.gov.br/SiteBNDES/export/sites/default/.../peadx.pdf> Acesso em 02 de abril de 2022

Brasil. Lei no 12.305, de 2 de agosto de 2010. Disponível em: <http://www.planalto.gov.br/ccivil_03/_ato2007-2010/2010/lei/l12305.html>. Acesso em: 02 de abril de 2022.

CAZAN, C.; COSNITA, M.; ISAC, L. The influence of temperature on the performance of rubber - PET-HDPE waste - based composites with different inorganic fillers. Journal of Cleaner Production, v. 20, p. 1030-1040, 2018.

COELHO, K.V.S.; LIBANO, E.V.D.G.; FILHO, F.G.R.; SANTOS, S.F.; PEREIRA, P.S.C.; BASTOS, D.C. Development of wood plastic composite with reduced water absorption. International Journal of Development Research, v. 11, pp.44547-44551, 2021.

Conama, Brasília. Conselho Nacional do Meio Ambiente. Resolução Conama, n. 66, 1986.

Dantas, R.L.F. Estudo morfológico da blenda polimérica poli (metacrilato de metila)/poli (tereftalato de etileno) reciclado (PMMA/PET). 2011. 90p. Dissertação (Mestre em Ciência e Engenharia de Materiais). Universidade Federal do Rio Grande do Norte, Rio Grande do Norte. Orientador: Edson Noriyuki Ito, 2011.

DE ALMEIDA, F.; CORREIA, A.; COSTA E SILVA, E.; LOPES, I., C.; SILVA, F.J.G. Compatibilization effect of organophilic clays in PA6/PP polymer blend. Procedia Manufacturing, v. 17, p. 1154-1161, 2018.

FERNADES, A.B., PEREIRA, P.S.C., BASTOS, D.C., Líbano, E.V.D.G. Wood-plastic composite based on post-consumer HDPE and vermiculite. Brazilian Journal of Development, v. 6, p. 82980-82987, 2020.

JASSIM, A.K. Recycling of polyethylene waste to produce plastic cement. Procedia manufacturing, v. 8, p. 635-642, 2017.

LI, X.; WANG, Y.; WANG, S.C.; ZHANG, Y.; MAO, S.; WANG, G.H.; LIU, J.X.; HUANG, L.J.; LI, H.; BELFIORE, L.A.; TANG, J.G. Effects of modified graphene oxide on thermal and crystallization properties of PET. Polymers, v. 10, p. 613-627, 2018.

LIBANO, E.V.D.G.; PEREIRA, P.S.C.; GONÇALVES, L.C.C.J.; COELHO, K.V.S. Processamento e avaliação das propriedades físicas, morfológicas e térrmicas de compósitos de PEAD reciclado e vermiculita Processing and evaluation of physical, morphological and termal. Engevista, v. 20, p. 296-311, 2018.

LU, C.; GAO, X.-P.; YAO, D.-H.; CAO, C.-L.; LUO, Y.-J. Improving flame retardancy of linear low-density polyethylene/nylon 6 blends via controlling localization of clay and intumescent flame-retardant. Polymer Degradation and Stability, v. 153, p. 75-87, 2018.

MACHADO, A.B.F.; Lima, A.M.; BASTOS, D.C.; PEREIRA, P.S.C.; LÍBANO, E.V.D.G. Avaliação estrutural e térmica de compósitos de polímero pós-consumo e argila nacional. Brazilian Journal of Development, v.7, p.13935-13953, 2021.

MASSON, T.J.; LIMA, R.S.L. Reciclagem do polipropileno para obtenção do compósito polimérico reforçado com pó de ostra. Engenharias: Metodologias e Práticas de Caráter Multidisciplinar 4, capítulo 4, p.40-57, 2021.

MEDERIC, P.; FNEICH, F.; VILLE, J.; AUBRY, T. Migration of clay and its role in droplet morphology establishment during melt mixing of clay polyethylene/polyamide nanocomposites. Applied Clay Science, v. 165, p. 257-263, 2018.

MÉLO, T.J.A.; ARAÚJO, E.M.; BRITO, G.F.; AGRAWAL, P. Development of nanocomposites from polymer blends: Effect of organoclay on the morphology and mechanical properties. Journal of alloys and compounds, v. 615, p. S389-S39, 2014.

MONTEIRO, J.R.G.; SIRELI, L.; LIBANO, E.V.D.G.; BASTOS, D.C.; PEREIRA, P.S.C. 2020. Recyclability by extrusion molding of high-density polyethylene from plastic bags. International Journal of Development Research, v. 10, p. 36709-36713, 2020.

RAVICHANDRAN, S.A.; RAJAN, V.P.; ARAVIND, P.V.; SEENIVASAN, A.; PRAKASH, D.G.; RAMAKRISHNAN, K. Characterization of terephthalic acid monomer recycled from post-consumer RPET polymer bottles, Macromolecular Symposia, v. 361, p. 30-33, 2016.

RIGAIL-CEDEÑO, A.; DIAZ-BARRIOS, A.; GALLARDO-BASTIDAS, J.; ULLAGUARI-LOOR, S.; MORALES-FUENTES, N. Recycled HDPE/PET Clay Nanocomposites. Key Engineering Materials. V. 821. p. 67-73, 2019.

RODRIGUES, N.P.; LIBANO, E.V.D.G.; BASTOS, D.C.; PEREIRA, P.S.C.P. 2020. Incorporação de PET pós-consumo em misturas de PEAD virgem compatibilizadas. Brazilian Applied Science Review, v. 4, p. 748-1764, 2020.

ROSNAN, R. M.; ARSAD, A. Effect of MMT concentrations as reinforcement on the properties of recycled PET/HDPE nanocomposites. Journal of Polymer Engineering, v. 33, p. 615-623, 2013.

SHAHRAJABIAN, H.; · SADEGHIAN, F. The investigation of alumina nanoparticles’ effects on the mechanical and thermal properties of HDPE/rPET/MAPE blends. International Nano Letters, v. 9, p. 213–219, 2019.

TANAKA, F.H.; CRUZ, S.A.; CANTO, L.B. Morphological, thermal and mechanical behavior of sepiolite-based poly (ethylene terephthalate)/polyamide 66 blend nanocomposites. Polymer Testing. v. 72, p. 298-307, 2018.

TORRES-HUERTA, A.M.; RAMÍREZ, D.P.; DOMÍNGUEZ-CRESPO, M.A.; ANGEL-LÓPEZ, D.D.; FUENTE, D.D.L. Comparative assessment of miscibility and degradability on PET/PLA and PET/chitosan blends. European Polymer Journal, v. 61, p. 285-299, 2014.

UTRACKI, L. A. 1989. Polymer Alloys and Blends: Thermodynamics and Rheology. Oxford University Press. NewYork.

WANG, D.; YANG, B.; CHEN, Q.-T.; CHEN, J.; SU, L.-F.; CHEN, P.; ZHENG, Z.-Z.; MIAO, J.-B.; QIAN, J.-S.; XIA, R.; SHI, Y. A facile evaluation on melt crystallization kinetics and thermal properties of low-density polyethylene (LDPE)/Recycled polyethylene terephthalate (RPET) blends. Advanced Industrial and Engineering Polymer Research, v. 2, p. 126-135, 2019.

YOUSFI, M.; SOULESTIN, J.; VERGNES, B.; LACRAMPE, M. F.; KRAWCZAK, P. Morphology and mechanical properties of PET/PE blends compatibilized by nanoclays: Effect of thermal stability of nanofiller organic modifier. Journal of Applied Polymer Science, v. 128, p. 2766–2778, 2013.

Downloads

Published

2023-04-11

How to Cite

Lima, A. M., Barros, G. de S., Santos, M. C. C., da Conceição, M. do N., Bastos, D. C., Pereira, P. S. da C., & Libano, E. V. D. G. (2023). Development of composites based on a blend of recycled HDPE/post-consumer PET and bentonite clay . Brazilian Journal of Development, 9(4), 13185–13200. https://doi.org/10.34117/bjdv9n4-041

Issue

Section

Original Papers