Caracterização microestrutural e resistência à corrosão da liga Fe-25Cr-Xti

Microstructural characterization and corrosion resistance of Fe-25Cr-xti alloy

Authors

  • Brendon Costa Barreto
  • Thácylla Jamile Mecenas de Jesus
  • Michelle Cardinale Souza Silva Macedo
  • Sandra Andreia Stwart de Araujo Souza

DOI:

https://doi.org/10.34117/bjdv8n11-034

Keywords:

Titânio, microestrutura, refino de grão, camada passiva, corrosão localizada

Abstract

A adição de ti em aço inoxidável ferrítico possui efeito benéfico no refino de grão e propicia melhoria na resistência à corrosão. O efeito da incorporação de 0,4 e 0,6% de Ti na liga Fe-25Cr foi investigado através de técnicas de microscopia, ensaio de imersão com variação de temperatura e ensaio eletroquímico. Os resultados indicam maior refino de grão na concentração de 0,4% de Ti, além disso foi observado que o titânio possui papel importante na melhoria da resistência à corrosão por frestas e por pites.

References

American Society for Testing and Materials, ASTM G 48. Standard test methods for pitting and crevice corrosion resistance of stainless steels and related alloys by use of ferric chloride. 2020.

AZEVEDO, C. R. F.; PADILHA, A. F. The most frequent failure causes in super ferritic stainless steels: are they really super? Procedia Structural Integrity, v. 17, p. 331-338, 2019.

CALABOKIS, O. P.; DE LA ROSA; Y. N.; LEPIENSKI, C. M.; CARDOSO, R. P.; BORGES, P. C. Crevice and pitting corrosion of low temperature plasma nitrided UNS S32750 super duplex stainless steel. Surface & Coatings Technology, v. 413, p. 1-13, 2021.

CRAMER, S. D.; COVINO, B. S.; ASM INTERNATIONAL. Corrosion : materials. Materials Park e ASM Handbook, Ohio, 2005.

DASTGERDI, A. A.; BOLZON, F. Experimental design to study the influence of temperature, pH, and chloride concentration on the pitting and crevice corrosion of UNS S30403 stainless steel. Corrosion Science, v. 159, p. 1-9, 2019.

FONTANA, M.G. Corrosion Engineering. McGrawHill, Singapore, ed. 3, 1987.

FU, J; CUI, K.; LI, F.; WANG, J.; WU, Y. Texture and anisotropic mechanical properties of ferritic stainless steel stabilized with Ti and Nb. Materials Chacracterization, v. 159, 2020.

FUKUDA, T. Effect of titanium carbide precipitates on the ductility of 30% mass chromium ferritic steels. Materials Transactions,v. 44, n. 6, p. 1153-1158, 2003.

GAO, F.; LIU, Z. Y.; LIU, H. T.; WANG, G. D. .Effect of the size and dispersion of precipitates formed in hot rolling on recrystallization texture in ferritic stainless steels, Journal of Materials Science, v. 48, p. 2404-2415, 2013.

GENTIL, V. Corrosao. LTC, Rio de Janeiro-BR, 2007.

GEORGE, G; SHAIK, H. Corrosion of Austenitic Stainless Steels: Introduction to Austenitic Stainless Steels. (H.S. KHATAK, H. S; RAJ, B.). Woodhead Publishing, Inglaterra, 2002.

KAMACHI MUDALI, U; PUJAR, M. J. Corrosion of Austenitic Stainless Steels: Pitting Corrosion of Austenitic Stainless Steels and Their Weldments. (H.S. KHATAK, H. S; RAJ, B.). Woodhead Publishing, Inglaterra, 2002.

KANG, Y.; MAO, W. M.; CHEN, Y. J.; JING, J.; CHENG, M. Effect of Ti contente on grain size and mechanical properties of UNS S44100 ferritic stainless steel. Materials Science & Engineering A, v. 677, p. 211-221, 2016.

LEI L.; SUN, Y.; ZHENG, K.; WANG, X.; HE, P.; LIU, Y.; YAO, Q.; YIN, L.; WAN, Y.; LI, J.; JIANG, Y. A comparative study on the critical pitting criteria of a super ferritic stainless steel at different temperatures in chloride or bromide solution. Corrosion Science, v. 183, p. 1-14, 2021.

LOPES-OJEDA, L.; VARGAS-GUTIERREZ, G. High wear resistance and better pitting corrosion resistance of AISI 316L stainless steel by a self-protective oxy-nitrocarburizing paste. Journal of Materials Research and Technology, v. 16, p. 1803-1813, 2022.

LU, H-H.; GUO, H.; LIANG, W.; LI, J.; ZHANG, G.; LI, T. High-temperature Laves precipitation and its effects on recrystallisation behaviour and Lüders deformation in super ferritic stainless steels. MaTerials and Design, v. 188, p. 1-12, 2020.

MA, L.; HU, S.; SHEN, J.; HAN, J.; ZHU, Z. Effects of Cr Content on the Microstructure and Properties of 26Cr–3.5Mo–2Ni and 29Cr–3.5Mo–2Ni Super Ferritic Stainless Steels. Journal of Materials Science & Technology, p. 1-17, 2016a.

MA, L.; HU, S.S; SHEN, J.Q.; HAN, J. Han, Effects of annealing temperature on microstructure, mechanical properties and corrosion resistance of 30% Cr super ferritic stainless steel. Mater. Lett, v. 184, p. 204–207, 2016b.

MA, X.; ZHAO, J.; DU, W.; ZHANG, X.; JIANG, L.; JIANG, Z. Quantification of texture-induced ridging in ferriticstainless steels 430 and 430LR during tensile deformation. Journal of Materials Research and Technology, v. 8, n. 2, p. 2041-2051, 2019.

MALLAIAHA, G.; RAVINDER REDDY, P.; KUMAR, A. Influence of titanium addition on mechanical properties, residual stresses and corrosion behaviour of AISI 430 grade ferritic stainless steel GTA welds. Procedia Materials Science, v. 6, p. 1740-1751, 2014.

MOURA, L. B.; NEGREIROS, Y. S. Computational thermodynamic analysis of secondary phases in super ferritic stainless steels. Journal of Materials Research and Technology, v. 2, p. 282-287, 2013.

NAA, E-Y.; KOB, J-Y.; BAIK, S-Y .Electrochemical evaluation of crevice corrosion of 430 ferritic stainless steel using the microcapillary tube technique. Desalination, v. 186, p. 65–74, 2005.

NICHOL, T.J.; Mechanical properties of a 29 Pct Cr–4 PctMo–2 Pct Ni ferritic stainless steel, Metall. Trans. A, v. 8, p. 229–237, 1997.

NUNES, L. P. Fundamentos de Resistencia a Corrosão. Interciência, ed. 1, 2007.

Olubamb, P. A.; Potgieter, J. H.;; Cornish, L. Corrosion behaviour of superferritic stainless steels cathodically modified with minor additions of ruthenium in sulphuric and hydrochloric acids. Materials and Design, v. 30, p. 1451-1457, 2009.

PARK, J. O.; MATSCH, S.; BÖHNI, H. Effects of Temperature and Chloride Concencration on Pit Initiation and Early Pit Growth of Stainless Steel. J. Electrochem. Soc., v. 149, p. B34-B39, 2002.

PREMACHANDRA, K.; CARTIE, M. B.; ERIC, R. H. Effect of stabilising elements on formation of σ phase in experimental ferritic stainless steels containing 39%Cr, Mater. Sci. Technol, v. 8, p. 437–442, 2013.

RODRIGUES, D. G.; DE ALCANTARA, C. M.; DE OLIVEIRA, T. R.; GONZALEZ, B. M. The effect of grain size and initial texture on microstructure, texture, and formability of Nb stabilized ferritic stainless steel manufactured by two-step cold rolling. Journal of Materials Research and Technology, v. 8, p. 4151-24162, 2019.

SINCLAIR, C. W.; MITHIEUX, J. D.; SCHMITT, J. H.; BRECHET, Y. Recrystallization of stabilized ferritic stainless steel sheet. Metallurgical and Materials Transactions A, v. 36, p. 3205–3215, 2005.

WIDYANTO, B.; WAHYUNDA, M.; SURATMAN, R. Study of Temperature and Chloride Concentration Effect on Pitting Corrosion. 20th International Corrosion Conferece, 2017.

ZHOU, Y.; ENGELBERG, D. L. Time-lapse observation of pitting corrosion in ferritic stainless steel under bipolar electrochemistry control. Journal of Electroanalytical Chemistry, v. 899, p. 115599-115605, 2021.

Published

2022-11-03

How to Cite

Barreto, B. C., Jesus , T. J. M. de, Macedo, M. C. S. S., & Souza, S. A. S. de A. (2022). Caracterização microestrutural e resistência à corrosão da liga Fe-25Cr-Xti : Microstructural characterization and corrosion resistance of Fe-25Cr-xti alloy. Brazilian Journal of Development, 8(11), 71275–71294. https://doi.org/10.34117/bjdv8n11-034

Issue

Section

Original Papers