Estudo da lixiviação ácida de catalisador de craqueamento catalítico desativado para remoção de lantânio / Evaluation of electrochemical extraction of metals in deactivated catalytic cracking catalyst
DOI:
https://doi.org/10.34117/bjdv8n7-236Keywords:
catalisador desativado, catalisador desativado, lixiviação ácida, lixiviação ácida, micro-ondas, micro-ondas, peróxido de hidrogênio, peróxido de hidrogênio, lantânio., lantânio.Abstract
Este estudo avaliou a lixiviação ácida convencional e lixiviações ácidas associadas a peróxido de hidrogênio e micro-ondas, visando maior recuperação de lantânio de catalisador desativado utilizado em craqueamento catalítico fluidizado de petróleo. Os resultados indicaram que a utilização de micro-ondas promoveu uma recuperação de lantânio 74,8% superior quando comparada à lixiviação ácida simples, e 41,3% superior à lixiviação associada ao peróxido de hidrogênio.
References
Abreu, R. D.; Morais, C. A. (2010). Purification of rare earth elements from monazite sulphuric acid leach liquor and the production of high-purity ceric oxide. Minerals Engineering, 23, 536-540. https://doi.org/10.1016/j.mineng.2010.03.010
Afonso, J. C.; Pontes, A. B.; Santos, E. S.; Menezes, M. S. Aguiar, R. M. (2004). Reciclagem Química de zeólitas comerciais desativadas. Química Nova, 27(2), 315-319. https://doi.org/10.1590/S0100-40422004000200024
Akcil, A.; Vegliò, F.; Ferella, F.; Okudan, M. D.; Tuncuk, A. (2015). A review of metal recovery from spent petroleum catalyst and ash. Waste Management, 45, 420-433. https://doi.org/10.1016/j.wasman.2015.07.007
Almeida, E.; Secchi, A. R. (2011). Dynamic optimization of a FCC converter unit: numerical analysis. Brazilian Jounal of Chemical Engineering, 28(1), 117-136. https://doi.org/10.1590/S0104-66322011000100014
Andrade, R. H. P. (2015). Terras raras. In: LIMA, T. M.; NEVES, C. A. R. Sumário Mineral 2015. Brasília: Departamento Nacional de Produção Mineral, 35, 108-109.
Bertuol, D. A.; Bernardes, A. M.; Tenório, J. A. S. (2009). Spent NiMH batteries – The role of selective precipitation in the recovery of valuable metals. Journal of Power Sources, 193, 914-923. https://doi.org/10.1016/j.jpowsour.2009.05.014
Busca, G., Riani, P., Garbarino, G., Ziemacki, G., Gambino, L., Montanari, E., Millini, R. (2014). The state of nickel in spent Fluid Catalytic Cracking catalysts. Appl. Cat. A, 486, 176–186. https://doi.org/10.1016/j.apcata.2014.08.011
Deniz, A.B.C., Valt, R.B.G, Kaminari, N.M.S., Ponte, M.J.J.S., Ponte, H.A. (2018). Parameters of an electrokinetic reactor design for vanadium recovery from fluid catalytic cracking catalysts. Sep. Purif. Technol., 193, 297–302. https://doi.org/10.1016/J.SEPPUR.2017.10.057
Godoi, L., Ponte, H.A., Ponte, M.J.J.S., Sanches, L.S., Valt, R.B.G., Leonel, R.F. (2018). Electroremediation of deactivated catalysts from fluidized catalytic cracking for vanadium removal – the effect of a dual cathode chamber reactor. Braz. J. Chem. Eng., 35, 63 – 68. https://doi.org/10.1590/0104-6632.20180351s20160388
Guisnet, M.; Ribeiro, F. R. (2004). Zeólitos - Um nanomundo a serviço da catálise. Lisboa: Fundação Calouste Gulbenkian.
Innocenzi, V., Ferella, F., Michelis, I., Veglio, F. (2015). Treatment of fluid catalytic cracking spent catalysts to recover lanthanum and cerium: Comparison between selective precipitation and solvent extraction. J. Ind. Eng. Chem., 24, 92–97. https://doi.org/10.1016/J.JIEC.2014.09.014
Innocenzi, V.; Vegliò, F. (2012). Recovery of rare earths and base metals from spent nickel-metal hydride batteries by sequential sulphuric acid leaching and selective precipitations. Journal of Power Sources, 211, 184-191. https://doi.org/10.1016/j.jpowsour.2012.03.064
Jha, M. K., Kumari, A., Panda, R., Kumar, J. R., Yoo, K., Lee, J. Y. (2016). Review on Hidrometallurgical Recovery of Rare Earth Metals. Hidrometallurgy, 161, 77-101. https://doi.org/10.1016/j.hydromet.2016.01.003
Leonel, R.F., Valt, R.B.G., Godoi, L., Ponte, M.J.J.S., Ponte, H.A. (2015). Efeito da aplicação da eletrorremediação na estrutura e nos contaminantes de catalisador desativado. Avaliação por técnicas de RMN, RPE, DRX e FRX. Eclet. Quim., 40, 86-94. https://doi.org/10.26850/1678-4618eqj.v40.1.2015.p86-94
Lu,G., Lu, X., Liu, P. (2020). Recovery of rare earth elements from spent fluid catalytic cracking catalyst using hydrogen peroxide as a reductant. Minerals Engineering, 145, 106104. https://doi.org/10.1016/J.MINENG.2019.106104
Maidel, M., Ponte, M.J.J.S., Ponte, H.A. (2019). Recycling lanthanum from effluents of electrokinetic treatment of FCC spent catalyst, using a selective precipitation technique. Sep. Pur. Tech., 210, 251–257. https://doi.org/10.1016/J.SEPPUR.2018.08.001
Muddanna, M.H., Baral, S.S. (2019). A comparative study of the extraction of metals from the spent fluid catalytic cracking catalyst using chemical leaching and bioleaching by Aspergillus niger. Journal of Environmental Chemical Engineering, 7 (5), 103335. https://doi.org/10.1016/J.JECE.2019.103335
Provazi, K.; Campos, B. A.; Espinosa, D. C. R.; Tenório, J. A. S. (2011). Metal separation from mixed types of batteries using selective precipitation and liquid-liquid extraction techniques. Waste Management, 31, 59-64. https://doi.org/10.1016/j.wasman.2010.08.021
Sadeghi, S.M, Jesus, J., Pinto, E., Almeida, A.A., Soares, H.M.V.M. (2020). A simple, efficient and selective process for recycling La (and Al) from fluid cracking catalysts using an environmentally friendly strategy. Minerals Engineering, 156, 106375. https://doi.org/10.1016/J.MINENG.2020.106375
Shahrabi-Farahani, M.; Yaghmaei, S.; Mousavi, S. M.; Amiri, F. (2014). Bioleaching of heavy metals from a petroleum spent catalyst using Acidithiobacillus thiooxidans in a slurry bubble column bioreactor. Separation and Purification Technology, 132, 41-49. https://doi.org/10.1016/J.SEPPUR.2014.04.039
Silva Filho, S.H., Bieseki, Maia, A.A.B., Pergher, S.B.C. (2015). Synthesis of zeolite a with high degree of structural order from a kaolin waste from the Jari region. Perspectiva, 39(147), 67-72. https://www.uricer.edu.br/site/pdfs/perspectiva/147_527.pdf
Souza-Aguiar, E.F.; Trigueiro, F.E.; Zotin, F.M.Z. (2013). The role of rare earth elements in zeolites and cracking catalysts. Catalysis Today, 218-219, 115-122. https://doi.org/10.1016/j.cattod.2013.06.021
Szklo, A., Uller, V.C. (2008). Fundamentos do Refino de Petróleo: Tecnologia e Economia. 2. ed. Rio de Janeiro: Interciência.
Valt, R.B.G., Diogenes, A.N., Sanches, L.S., Kaminari, N.M.S., Ponte, M.J.J.S., Ponte, H.A. (2015). Acidic removal of metals from fluidized catalytic cracking catalyst waste assisted by electrockinetic treatment. Braz. J. Chem. Eng., 32,465–473. https://doi.org/10.1590/0104-6632.20150322s00003459
Vogt, E.T.C.; Weckhuysen, B.M. (2015). Fluid catalytic cracking: recent developments on the grand old lady zeolite catalysis. Chemical Society Reviews, 44, 7342-7370. https://doi.org/10.1039/C5CS00376H
