Aplicação da energia solar na pirólise catalítica In Situ de microalgas / Application of solar energy in In Situ catalytic pyrolysis of microalgae

Authors

  • Laiane Alves de Andrade
  • Janaína Miranda Barbosa
  • Yanne Novais Kyriakidis
  • Marcos Antonio de Souza Barrozo
  • Luiz Gustavo Martins Vieira

DOI:

https://doi.org/10.34117/bjdv8n2-442

Keywords:

pirólise, energia solar, microalgas, catálise, termoconversão.

Abstract

A pirólise catalítica in situ das microalgas Chlamydomonas reinhardtii e Spirulina platensis foram estudadas usando como catalisador a hidrotalcita e a energia solar como fonte de aquecimento. O objetivo do trabalho foi caracterizar e avaliar o comportamento de cada microalga durante o processo catalítico de termoconversão. Para tal, a caracterização das matérias primas foi realizada segundo diversas técnicas. Adicionalmente, testes de pirólise solar foram realizados usando uma unidade experimental composta por um paraboloide espelhado capaz de concentrar a radiação solar no ponto focal onde o reator estava localizado. Os rendimentos dos de sólido, líquido e gás foram quantificados. Os produtos da pirólise destas duas microalgas foram comparados. A baixa quantidade de biomassa favoreceu a produção de líquido para Chlamydomonas e Spirulina, e a porcentagem intermediária e alta de catalisador resultaram em grandes rendimentos líquidos para ambas as microalgas. As composições químicas das microalgas foram responsáveis pela atuação do catalisador de forma distinta que culminou em produtos com diferentes características.

References

ADNAN, M. A.; HOSSAIN, M. M. (2018). “Gasification performance of various microalgae biomass–A thermodynamic study by considering tar formation using Aspen plus.” Energy Conversion and Management, 165, 783-793.

ANDRADE, L.A.; BARROZO, M.A.S.; VIEIRA, L.G.M. (2016), “A study on dynamic heating in solar dish concentrators.” Renewable Energy, 87, 501–508.

ANDRADE, L.A., BARROZO, M.A.S. VIEIRA, L.G.M. (2018a), “Catalytic solar pyrolysis of microalgae Chlamydomonas reinhardtii.” Solar Energy, 173, 928–938.

ANDRADE, L.A., BARROZO, M.A.S. VIEIRA, L.G.M. (2018b), “Characterization and product formation during the catalytic and non-catalytic pyrolysis of the green microalgae Chlamydomonas reinhardtii.” Renewable Energy, 119, 731–740.

BENSAID, S.; CENTI, G.; GARRONE, E.; PERATHONER, S., SARACCO, G.(2012), “Towards Artificial leaves for solar hydrogen and fuels from carbon dioxide”. ChemSusChem, 5, 500-521.

BIANCHINI, E., FABBRI, D., ROMBOLA, G. A., TORRI, C., GUERRIINI, F., PISTOCCHI, R., CALABRIA, R., MASSOLI, P. (2017). “Pyrolysis of spirulina and zeolite cracking over HZSM-5: An analytical investigation on the chemical route of bio-oil from cultivation to combustion.” J. Anal. Appl. Pyrol. Vol.126, p.230-238.

CHAGAS, M.B.E.; DORADO, C.; SERAPIGLIA, M.J.; MULLEN, A.C.; BOATENG, A.A.; MELO, A.F.M.; ATAÍDE, C.H. (2016), “Catalytic pyrolysis-GC/MS of Spirulina: Evaluation of a highly proteinaceous biomass source for production of fuels and chemicals.” Fuel, 179, 124-134.

CHEN, W. H., LIN, B. J., HUANG, M. Y., CHANG,J.S. (2015), “Thermochemical conversion of microalgal biomass into biofuels: a review.” Bioresource technology, 184, 314-327.

CHENG, S.; WEI, L.; ZHAO, X.; JULSON, J.; (2016) “Application, Deactivation, and Regeneration of Heterogeneous Catalysts in bio-oil upgrading. Catalysts, 6, 195.

DICKERSON, T., SORIA, J. (2013). “Catalytic fast pyrolysis: a review.” Energies, 6, 514-538.

HALLENBECK, P.C.; GROGGER, M.; MRAZ, M.; VEVERKA, D. (2016), “Solar biofuels production with microalgae.” Applied Energy, 179, 136–145.

LIU, G., LIAO, Y., WU, Y., MA, X., CHEN, L. (2017). “Characteristics of microalgae gasification through chemical looping in the presence of steam.” International Journal of Hydrogen Energy, 42, 22730-22742.

METTLER, M.S.; PAULSEN, A.D.; VLACHOS, D.G.; DAUENHAUER, P.J. (2012). “The chain length effect in pyrolysis: bridging the gap between glucose and cellulose”. Green Chem. Vol.14, p.1284–1288.

MOHAN, D.; PITTMAN, C.U.; STEELE, P.H.; (2006), “Pyrolysis of Wood / Biomass for Bio-oil : A Critical Review”, 20, 848–889.

MULEY, P.D.; HENKEL, C.E.; AGUILAR, G.; KLASSON, K.T.; BOLDOR, D. (2016), “Ex situ thermo-catalytic upgrading of biomass pyrolysis vapors using a traveling wave microwave reactor.”, Applied Energy, 183, 995–1004.

NYGÅRD, H.S. OLSEN, E.; (2012), “Review of thermal processing of biomass and waste in molten salts for production of renewable fuels and chemicals” International Journal of Low-Carbon Technolology, 7, 318–324.

SOARES, R. B.; ASSIS, T. I.; DASSOLER, A.; AMARANTE, L. M. (2019). “Levantamento bibliométrico e mapeamento da análise de ciclo de vida para microalgas: uma revisão da literatura”. Brazilian Journal of Development, v. 5, p. 32984-32995.

XIE, Q., ADDY, M., LIU, S., ZHANG, B., CHENG, Y., WAN, Y., LI, Y.; LIU, Y.; LIN, X.; CHEN, P.; RUAN, R. (2015). “Fast microwave-assisted catalytic co-pyrolysis of microalgae and scum for bio-oil production.” Fuel, 160, 577-582.

WANG, K; BROWN, R.C.; HOMSY, S.; MARTINEZ, L.; SIDHU, S. S. (2013), “Fast pyrolysis of microalgae remnants in a fluidized bed reactor for bio-oil and biochar production”. Bioresource Technology, 127, 494-499.

WANG, X.; TANG, X.; YANG, X. (2017). “Pyrolysis mechanism of microalgae Nannochloropsis sp. based on model compounds and their interaction”. Energy Convers. Manage. Vol.140, p.203–210.

WIYANTOKO, B.; KURNIAWATI, P.; PURBANINGTIAS, T.E.; FATIMAH, I. (2015), “Synthesis and Characterization of Hydrotalcite at Different Mg/Al Molar Ratios”. Procedia Chemistry, 17, 21–26.

ZAINAN, N.H.; SRIVATSA, S.C.; LI, F.; BHATTACHARYA, S. (2018). “Quality of bio-oil from catalytic pyrolysis of microalga Chlorella vulgaris.” Fuel. 223, 12-19.

ZEAITER, J., AHMAD, M. N., ROONEY, D., SAMNEH, B., SHAMMAS, E. (2015). “Design of an automated solar concentrator for the pyrolysis of scrap rubber.” Energy Conversion and Management, 101, 118-125.

ZENG, K., GAITHIER, D., SORIA,J., MAZZA, G., Flamant, G. ( 2017), “Solar Pyrolysis of Carbonaceous Feedstocks : A Review.” Solar Energy ,156, 73–92.

Published

2022-02-27

How to Cite

Andrade, L. A. de, Barbosa, J. M., Kyriakidis, Y. N., Barrozo, M. A. de S., & Vieira, L. G. M. (2022). Aplicação da energia solar na pirólise catalítica In Situ de microalgas / Application of solar energy in In Situ catalytic pyrolysis of microalgae. Brazilian Journal of Development, 8(2), 15209–15222. https://doi.org/10.34117/bjdv8n2-442

Issue

Section

Original Papers